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81.
Specific interactions in blends containing Chitosan and functionalized polymers. Molecular dynamics simulations 总被引:2,自引:0,他引:2
Chitosan (CS)/poly(vinyl alcohol) (PVA) and Chitosan/poly(2-hydroxyethyl methacrylate) (P2HEM) blends have been studied through molecular dynamic simulations. In a previous work it was found miscibility between these polymers and it was attributed to hydrogen bonding formation. However, the experimental information obtained was not enough to know which of the interacting groups of Chitosan, i.e. -CH2OH or -NH2, are responsible of the interaction. Therefore, we have performed molecular dynamics simulation runs of 1 ns in order to calculate radial distribution functions (RDF) for the groups tentatively involved in the interaction. The results are correlated with our previous experimental data. This way, we have obtained a more precise conclusive information about the interactions involved as function of the blends composition. For low compositions of PVA and P2HEM the interaction is predominantly with the hydroxymethyl groups of CS while as the composition of PVA and P2HEM increases, the interaction with the amine groups increases. 相似文献
82.
George Weiss 《Mathematics of Control, Signals, and Systems (MCSS)》1991,4(2):193-203
We give an elementary proof of the well-known fact that shift-invariant operators onL
2[0, ∞) are represented by transfer functions which are bounded and analytic on the right open half-plane. We prove a generalization
to Banach space-valuedL
p
-functions, where 1≤p<∞. We show that the result no longer holds forp=∞.
This research was supported partially by the Weizmann Fellowship, and partially by the Air Force Office of Scientific Research
under Contract F49620-86-C-0111. 相似文献
83.
大规模训练数据的支持向量机学习新方法 总被引:1,自引:1,他引:0
支持向量机不能直接对大规模的训练数据进行学习。提出一种新的减小样本集规模的方法;在映射后的高维空间中寻找两种类别的交界部分,交界部分上的样本作为学习样本。并且指出,不需涉及具体映射的形式只用核函数即可找到交界部分的样本。实验表明,新方法优于直接在低维样本空间中寻找交界部分样本的方法。 相似文献
84.
Hinshaw Stephen P.; Carte Estol T.; Fan Catherine; Jassy Jonathan S.; Owens Elizabeth B. 《Canadian Metallurgical Quarterly》2007,21(2):263
The current study prospectively followed girls with attention-deficit/hyperactivity disorder (ADHD), along with a matched comparison sample, 5 years after childhood neuropsychological assessments. Follow-up neuropsychological measures emphasized attentional skills, executive functions, and language abilities. Paralleling childhood findings, the childhood-diagnosed ADHD group displayed moderate to large deficits in executive/attentional performance as well as in rapid naming relative to the comparison group at follow up (Mage 14.2 years). ADHD-inattentive versus ADHD-combined contrasts were nonsignificant and of negligible effect size, even when a refined, sluggish cognitive tempo subgroup of the inattentive type was examined. Although ADHD versus comparison group differences largely withstood statistical control of baseline demographics and comorbidities, control of childhood IQ reduced executive function differences to nonsignificance. Yet when the subset of girls meeting diagnostic criteria for ADHD in adolescence was compared with the remainder of the participants, neuropsychological deficits emerged even with full statistical control. Overall, childhood ADHD in girls portends neuropsychological and executive deficits that persist for at least 5 years. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
85.
86.
张小蹦 《西安邮电学院学报》2008,13(1):139-140,148
本文的主要目的是利用初等方法研究Smarandache可乘函数在简单数集中的均值性质,并给出一个有趣的渐近公式。 相似文献
87.
A method is considered to solve a conditional optimization problem with a linear-fractional objective function over permutations.
The performance of sub algorithms to solve this problem is evaluated. The practical efficiency of the algorithm is analyzed
by conducting numerical experiments.
__________
Translated from Kibernetika i Sistemnyi Analiz, No. 4, pp. 133–146, July–August 2007. 相似文献
88.
首先运用遗传算法,在一定的初边值条件下通过对比试验实测值与解析解确定出导热系数与比热的函数值α(λ,c,ρ),再利用已确定出的系数α,通过遗传数值法计算值与实测值比较,进而确定出等效导热系数λ与比热c。 相似文献
89.
We propose a general modeling framework to evaluate the performance of cache consistency algorithms. In addition to the usual hit rate, we introduce the hit* rate as a consistency measure, which captures the fraction of non-stale downloads from the cache. We apply these ideas to the analysis of the fixed TTL consistency algorithm in the presence of network delays. The hit and hit* rates are evaluated when requests and updates are modeled by renewal processes. Classical results on the renewal function lead to various bounds. 相似文献
90.
L. M. CRUZ-ORIVE 《Journal of microscopy》2005,219(1):18-28
A new principle is presented to generate isotropic uniform random (IUR) test lines hitting a geometric structure in three-dimensional space (3D). The principle therefore concerns the estimation of surface area, volume, membrane thickness, etc., of arbitrary structures with piecewise smooth boundary. The principle states that a point-sampled test line on an isotropic plane through a fixed point in 3D is effectively an invariant test line in 3D. Particular attention is devoted to the stereology of particles, where an alternative to the surfactor method is obtained to estimate surface area. An interesting case arises when the particle is convex. The methods are illustrated with synthetic examples. 相似文献